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题名: Superhalogen properties of BS2- and BSO-: photoelectron spectroscopy and theoretical calculations
作者: Zhao, Li-Juan1; Xu, Hong-Guang1; Feng, Gang1; Wang, Peng1; Xu, Xi-Ling1; Zheng, Wei-Jun1
刊名: PHYSICAL CHEMISTRY CHEMICAL PHYSICS
发表日期: 2016-02-28
卷: 18, 期:8, 页:6175-6181
收录类别: SCI
英文摘要: We investigate BS2- and BSO- clusters using photoelectron spectroscopy and theoretical calculations. The electron affinities of BS2 and BSO are measured to be 3.80 +/- 0.03 and 3.88 +/- 0.03 eV, respectively, higher than those of halogen atoms. Thus, BS2 and BSO can be considered as superhalogens. The comparison of experimental and theoretical results confirmed that the ground state structures of BS2-, BSO-, and their neutrals are all linear. Analyses of natural bond orbitals suggest that both BS2- and BSO- have dual 3c-4e pi hyperbonds.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35907
Appears in Collections:分子反应动力学实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
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