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题名: Superspreading on Immersed Gel Surfaces for the Confined Synthesis of Thin Polymer Films
作者: Zhang, Pengchao1, 2, 3; Zhang, Feilong2; Zhao, Chuangqi1; Wang, Shutao3; Liu, Mingjie1; Jiang, Lei1, 2, 3
关键词: hydrogels ; organogels ; superspreading ; thin polymer films ; under-liquid
刊名: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
发表日期: 2016-03-07
卷: 55, 期:11, 页:3615-3619
收录类别: SCI
英文摘要: Liquid spreading is of significant interest in science and technology. Although surface topography engineering and liquid surface-tension regulating can facilitate spreading, the spreading layers in these strategies are inevitably inhomogeneous or contaminated with surfactants. Herein, we show a general strategy to realize the superspreading of liquids on mutually soluble gel surfaces. The cooperation of the hydraulic pressure under liquid phase and liquid-like property of gel surfaces can dramatically eliminate the local pinning effect and enhance the advancement of three-phase contact line, thus forming stable and homogeneous superspreading liquid layers. Such liquid layers can be converted into various functional thin polymer films with controlled thicknesses (nm- to mu m-scale) through one-step polymerization of the reactants. Our strategy offers opportunities for large-scale synthesis of versatile functional thin films for various applications.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35885
Appears in Collections:有机固体实验室_期刊论文

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作者单位: 1.Beihang Univ, Key Lab Bioinspired Smart Interfacial Sci & Tech, Minist Educ,Sch Chem & Environm, Int Res Inst Multidisciplinary Sci, Beijing 100191, Peoples R China
2.Chinese Acad Sci, BNLMS, Key Lab Organ Solids, Inst Chem, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Tech Inst Phys & Chem, Lab Bioinspired Smart Interface Sci, Beijing 100190, Peoples R China
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