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题名: Effects of Molecular Structures on Aggregation Behavior of Gemini Surfactants in Aqueous Solutions
作者: Fan Ya-Xun1; Han Yu-Chun1; Wang Yi-Lin1
关键词: Gemini surfactant ; Molecular structure ; Aggregation behavior ; Aggregate structure
刊名: ACTA PHYSICO-CHIMICA SINICA
发表日期: 2016-01-15
卷: 32, 期:1, 页:214-226
收录类别: SCI
英文摘要: Gemini surfactants consist of two amphiphilic moieties covalently connected by a spacer at the level of the head groups. Compared with the corresponding monomeric surfactants, gemini surfactants exhibit higher surface activity, possess unique structural variations, display special aggregate transitions, and form variable aggregate structures. Their aggregation ability and aggregate structures can be effectively adjusted by varying their molecular structures, which results in different intra- or intermolecular interactions. This short review is focused on the behavior of gemini surfactants in aqueous solutions reported in recent years, and summarizes the effects of different molecular structures, including spacers, hydrophobic chains, hydrophilic headgroups, counterions, and functional groups. The mechanisms and trends of the interactions in gemini surfactants are also presented.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35871
Appears in Collections:胶体、界面与化学热力学实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Colloid Interface & Chem Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
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