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题名: Primary investigation of the optical limiting performance of cyclo[8]pyrrole with a wide optical limiting window
作者: Xu, H.1; Zhao, S. Q.1; Ren, Y.1; Xu, W.2; Zhu, D. B.2; Jiang, J. Z.1; Cai, J. F.3
刊名: RSC ADVANCES
发表日期: 2016
卷: 6, 期:25, 页:21067-21071
收录类别: SCI
英文摘要: Cyclo[8] pyrrole (CP) was prepared and its UV/vis spectral and optical limiting properties for ns light pulse were investigated with Z-scan technical. Our experiments show that CP has good solubility in organic solvents, and its Q band absorption shows an obvious red shift to the NIR region at about 1100 nm compared with normal porphyrin. Studies on transient absorption spectra, photophysical parameters and optical limiting properties indicate that the compound exhibits good optical limiting performance under variable conditions. Briefly, it shows a reverse saturable absorber with the limiting threshold of 1.8 J cm(-2) at 1064 nm in dichloromethane; interestingly, it displays limiting properties at both 532 nm and 1064 nm after treatment with NaOH.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35867
Appears in Collections:有机固体实验室_期刊论文

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作者单位: 1.Cent S Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China
2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Organ Solids, Beijing 100080, Peoples R China
3.Univ S Florida, Dept Chem, Tampa, FL 33620 USA
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