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题名: Janus Nanoparticles of Block Copolymers by Emulsion Solvent Evaporation Induced Assembly
作者: Deng, Renhua1, 2; Li, Hui3, 4; Zhu, Jintao2; Li, Baohui3, 4; Liang, Fuxin1; Jia, Fan1; Qu, Xiaozhong1; Yang, Zhenzhong1
刊名: MACROMOLECULES
发表日期: 2016-02-23
卷: 49, 期:4, 页:1362-1368
收录类别: SCI
英文摘要: We present a facile approach toward straightforward synthesis of Janus nanoparticles (NPs) of poly(4-vinylpyridine)-based block copolymers by solvent evaporation induced assembly within emulsion droplets. Formation of the Janus NPs is arisen from the synergistic effect between solvent selectivity and interfacial selectivity. This method is robust without the requisites of narrow molecular weight distribution and specific range of block fraction of the copolymers. Janus NPs can also be achieved from mixtures of copolymers, whose aspect size ratio and thus Janus balance are finely tunable. The Janus NPs are capable to self-assemble into ordered superstructures either onto substrates or in dispersions, whose morphology relies on Janus balance.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35838
Appears in Collections:高分子物理与化学实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
2.Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Key Lab Mat Chem Energy Convers & Storage, Minist Educ, Wuhan 430074, Peoples R China
3.Nankai Univ, Sch Phys, Tianjin 300071, Peoples R China
4.Nankai Univ, Key Lab Funct Polymer Mat, Minist Educ, Tianjin 300071, Peoples R China
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