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题名: A Facile Approach to Optically Active Hydroquinoline-2-carboxylates by a One-Pot Asymmetric Michael/Transamination/Cyclization Process
作者: Rong, Chao1; Pan, Hongjie1; Liu, Mao1; Tian, Hua1; Shi, Yian1, 2
关键词: cyclization ; Michael addition ; organocatalysis ; transamination
刊名: CHEMISTRY-A EUROPEAN JOURNAL
发表日期: 2016-02-24
卷: 22, 期:9, 页:2887-2891
收录类别: SCI
英文摘要: An efficient one-pot synthesis of optically active hydroquinoline-2-carboxylates from 1,3-cyclohexanediones, ,-unsaturated -keto ester, and benzylamine in the presence of a chiral base catalyst and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) with good diastereoselectivity and high enantioselectivity is described. The reaction proceeds by a sequential asymmetric Michael/transamination/cyclization process.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35821
Appears in Collections:分子识别与功能实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China
2.Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA
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