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题名: High-internal-phase emulsions stabilized by metal-organic frameworks and derivation of ultralight metal-organic aerogels
作者: Zhang, Bingxing1; Zhang, Jianling1; Liu, Chengcheng1; Peng, Li1; Sang, Xinxin1; Han, Buxing1; Ma, Xue1; Luo, Tian1; Tan, Xiuniang1; Yang, Guanying1
刊名: SCIENTIFIC REPORTS
发表日期: 2016-02-19
卷: 6
收录类别: SCI
英文摘要: To design high-internal-phase emulsion (HIPE) systems is of great interest from the viewpoints of both fundamental researches and practical applications. Here we demonstrate for the first time the utilization of metal-organic framework (MOF) for HIPE formation. By stirring the mixture of water, oil and MOF at room temperature, the HIPE stabilized by the assembly of MOF nanocrystals at oil-water interface could be formed. The MOF-stabilized HIPE provides a novel route to produce highly porous metal-organic aerogel (MOA) monolith. After removing the liquids from the MOF-stabilized HIPE, the ultralight MOA with density as low as 0.01 g.cm(-3) was obtained. The HIPE approach for MOA formation has unique advantages and is versatile in producing different kinds of ultralight MOAs with tunable porosities and structures.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35820
Appears in Collections:胶体、界面与化学热力学实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, CAS Key Lab Colloid & Interface & Thermodynam, Inst Chem, Beijing Natl Lab Mol Sci, Zhongguancun North First St 2, Beijing 100190, Peoples R China
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