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题名: Photodissociation dynamics of ICH2Cl -> CH2Cl + I-star/I: photofragment translational spectroscopy at 304 and 277 nm
作者: Cheng, Min1; Lin, Dan1; Hu, Lili1; Du, Yikui1; Zhu, Qihe1
刊名: PHYSICAL CHEMISTRY CHEMICAL PHYSICS
发表日期: 2016-01-28
卷: 18, 期:4, 页:3165-3172
收录类别: SCI
英文摘要: The photodissociation dynamics of ICH2Cl -> CH2Cl + I-star/I at 304 and 277 nm has been investigated with our mini-TOF photofragment translational spectrometer with a weak acceleration field of <1 V cm(-1). Many peaks are resolved or partially resolved in the TOF spectra and the photofragment translational spectra (PTS) of both the I-star(P-2(1/2)) channel and the I(P-2(3/2)) channel. These resolved peaks are assigned to the C-Cl stretch vibrational states of the CH2Cl fragment. The rotational energy E-R of the CH2Cl fragment is highly excited due to its asymmetric structure. The value of E-R/E-T is measured to be about 0.71. In the I-star channel, the partitioning of the available energy E-avl into the translational energy E-T, the rotational energy E-R, and the vibrational energy E-V for each resolved vibrational state has been calculated.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35815
Appears in Collections:分子反应动力学实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
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