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题名: Chiral Frustrated Lewis Pairs Catalyzed Highly Enantioselective Hydrosilylations of 1,2-Dicarbonyl Compounds
作者: Ren, Xiaoyu1; Du, Haifeng1
刊名: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
发表日期: 2016-01-27
卷: 138, 期:3, 页:810-813
收录类别: SCI ; IC ; CCR
英文摘要: A highly enantioselective hydrosilylation of 1,2-dicarbonyl compounds was successfully realized for the first time utilizing the combination of tricyclohexylphosphine and chiral alkenylborane derived in situ from diyne as a frustrated Lewis pair catalyst. A variety of optically active a-hydroxy ketones and esters were obtained in 52-98% yields with 86-99% ees.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35807
Appears in Collections:分子识别与功能实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China
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