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题名: Synthesis and Structure of Corona[6](het)arenes Containing Mixed Bridge Units
作者: Fu, Zhan-Da1; Guo, Qjng-Hui1, 2; Zhao, Liang1; Wang, De-Xian2; Wang, Mei-Xiang1
刊名: ORGANIC LETTERS
发表日期: 2016-06-03
卷: 18, 期:11, 页:2668-2671
收录类别: SCI
英文摘要: A one-pot nucleophilic aromatic substitution reaction of 3,6-dichlorotetrazine with various diphenols and dibenzenethiols produced corona[4]arene[2]tetrazines that contain mixed oxygen, sulfide, methylene, and sulfone linkages. Macrocyclic ring transformations employing an inverse-electron-demand Diels-Alder reaction of tetrazine moieties with enamines and the subsequent sulfide oxidation reaction afforded diverse corona[4]arene[2]pyridazines. The acquired corona[6]arenes adopted three types of conformational structures in the crystalline state.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35796
Appears in Collections:分子识别与功能实验室_期刊论文

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作者单位: 1.Tsinghua Univ, Minist Educ, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China
2.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
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