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题名: N-Heterocyclic Carbene-Catalyzed [3+4] Annulation of Enals and Alkenyl Thiazolones: Enantioselective Synthesis of Thiazole-Fused epsilon-Lactones
作者: Liang, Zhi-Qin1; Yi, Liang1; Chen, Kun-Quan1; Ye, Song1
刊名: JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2016-06-03
卷: 81, 期:11, 页:4841-4846
收录类别: SCI
英文摘要: The bifunctional N-heterocyclic carbene catalyzed [3 + 4] annulation of enals and 5-alkenyl thiazolones was developed, giving, the corresponding thiazole-fused e-lactones in high yields with excellent diastereoselectivties and enantioselectivities. The thiazole-fused e-lactone could be isomerized to the spirocyclic thiazolone-cyclopentanone without erosion of enantioselectivity.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35789
Appears in Collections:分子识别与功能实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China
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