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题名: Metal-Free Hydrogen Atom Transfer from Water: Expeditious Hydrogenation of N-Heterocycles Mediated by Diboronic Acid
作者: Xia, Yun-Tao1, 2; Sun, Xiao-Tao1, 2; Zhang, Ling1, 2; Luo, Kai1, 2; Wu, Lei1, 2, 3, 4
关键词: diboronic acid ; hydrogen atom transfer ; metal-free ; nitrogen heterocycles ; water
刊名: CHEMISTRY-A EUROPEAN JOURNAL
发表日期: 2016-11-21
卷: 22, 期:48, 页:17151-17155
收录类别: SCI
英文摘要: A hydrogenation of N-heterocycles mediated by diboronic acid with water as the hydrogen atom source is reported. A variety of N-heterocycles can be hydrogenated with medium to excellent yields within 10min. Complete deuterium incorporation from stoichiometric D2O onto substrates further exemplifies the H/D atom sources. Mechanism studies reveal that the reduction proceeds with initial 1,2-addition, in which diboronic acid synergistically activates substrates and water via a six-membered ring transition state.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35697
Appears in Collections:其它_期刊论文

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作者单位: 1.Nanjing Agr Univ, Coll Sci, Jiangsu Key Lab Pesticide Sci, Nanjing 210095, Jiangsu, Peoples R China
2.Nanjing Agr Univ, Coll Sci, Dept Chem, Nanjing 210095, Jiangsu, Peoples R China
3.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
4.Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
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