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题名: Synthesis and self-assembly of novel oxacalix[2]arene[2]triazine amphiphiles
作者: Xu, Ruibin1, 3; Hou, Baoyong1; Wang, Dexian1, 3; Wang, Meixiang2
关键词: oxacalix[2]arene[2]triazine ; heteracalixaromatics ; amphiphile ; self-assembly
刊名: SCIENCE CHINA-CHEMISTRY
发表日期: 2016-10-01
卷: 59, 期:10, 页:1306-1310
收录类别: SCI
英文摘要: Heteracalixaromatics are an emerging generation of macrocyclic host molecules in supramolecular chemistry. As a typical example of heteracalixaromatics, oxacalix[2]arene[2]triazine adopts a shape-persistent 1,3-alternate conformation and can be easily functionalized. Taking it as a platform, a series of oxacalix[2]arene[2]triazine-based amphiphiles bearing long alkyl chains were synthesized through post-macrocyclization functionalization or 3+1 fragment coupling protocols. The self-assembly behavior of these amphiphiles in a mixture of tetrahydrofuran (THF) and water was investigated. Dynamic light scattering (DLS) measurements revealed that the size of the self-assembled aggregates is dependent on the structure of the amphiphiles. The long alkyl chain substituents and/or intermolecular hydrogen bonds were found to promote the self-assembly.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35663
Appears in Collections:分子识别与功能实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Beijing Natl Lab Mol Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China
2.Tsinghua Univ, Dept Chem, Key Lab Bioorgan Phosphorus Chem & Chem Biol, Minist Educ, Beijing 100084, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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