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题名: Modulating PCBM-Acceptor Crystallinity and Organic Solar Cell Performance by Judiciously Designing Small-Molecule Mainchain End-Capping Units
作者: Jiang, Bo1; Yao, Jiannian1; Zhan, Chuanlang1
关键词: end-capping ; bulk-size ; electron-donating/electron-accepting ; small-molecule ; PCBM crystallinity
刊名: ACS APPLIED MATERIALS & INTERFACES
发表日期: 2016-10-05
卷: 8, 期:39, 页:26058-26065
收录类别: SCI
英文摘要: In this article, we report that the bulk-size and electron-donating/electron-accepting nature of moieties, which are end-capping onto small-molecule donor mainchain, not only modulate the donor's absorption, molecular frontier orbitals, and phase ordering, but also effectively tune the PC71BM-acceptor phase crystallinity. Compared to the electron-deficient trifluoromethyl (SM-CF3) units on the diketopyrrolopyrrole (DPP) small molecule mainchain ends, the electron-rich methoxyl (SM-OCH3) units ending on the same mainchain help improve the PC71BM-acceptor phase short-range ordering. As a result, the-OCH3 capping small-molecule displays larger short-circuit current density (J(sc)) when blended with PC71BM (10.72 +/- 0.22 vs. 16.15 +/- 0.53 mA/cm(2)). However, the electron-donating nature of -OCH3 raises the donor HOMO level, which leads to a quite small open circuit voltage (V-oc) (0.624 vs. 0.881 V). Replacement of the -OCH3 with the large and weak electron-donating aromatic carbazolyl (SM-Cz) ones affords the small molecule of SM-Cz. The SM-Cz:PC71BM system affords a high V-oc of 0.846 V and a large J(sc) of 13.33 +/- 0.34 mA/cm(2) after thermal annealing, and hence gives a larger power conversion efficiency (PCE) of 6.26 +/- 0.13%, which is among the top values achieved so far from the DPP molecules. Taken together, these results demonstrate that engineering the end-capping units on small-molecule donor mainchain can effectively modulate the organic solar cell performance.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35658
Appears in Collections:光化学实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
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