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题名: Transient microstructure in long alkane segment polyamide: Deformation mechanism and its temperature dependence
作者: Wang, Lili1; Dong, Xia1; Huang, Miaoming1; Wang, Dujin1
关键词: Long chain polyamide ; Transient microstructure ; Temperature dependence
刊名: POLYMER
发表日期: 2016-08-05
卷: 97, 页:217-225
收录类别: SCI
英文摘要: Deformation-induced microstructure evolution of Polyamide 1012, with an emphasis on lamella development, polymorphism transition and molecular orientation, is investigated. When deformed above Tg (100 degrees C), a series of complex SAXS patterns are continuously identified at intermediate strain including four-point pattern, figure-8 pattern and X-shaped pattern, accompanied with two-bar pattern on the meridian, which corresponds to the transient microstructure. Such particular structure is resulted from the approach of tilted lamellae along the drawing direction, the insertion and the orientation of new lamellae. To investigate the temperature dependence, the microstructure developments at 30 degrees C (below Tg), 60 degrees C (close to Tg) and 100 degrees C (above Tg) are compared. Considering 38% enhancement of the fracture stress with elevated temperature (from 60 degrees C to 100 degrees C), the temperature dependence of particular SAXS patterns further suggests that the elongation above Tg favors higher level of stretching-induced crystallization and better aligned microfibrillar structure, which competes with thermal-induced increased chain mobility. Based on the comprehensive results, the correlation between microstructure and mechanical response has been successfully established, which is featured by the synchronous occurrence of transient structure with slight strain hardening. (C) 2016 Elsevier Ltd. All rights reserved.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35608
Appears in Collections:工程塑料实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Engn Plast, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
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