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题名: Cobalt-Catalyzed Peroxidation of 2-Oxindoles with Hydroperoxides
作者: Kong, De-Long1; Cheng, Liang1; Yue, Tao2; Wu, Hong-Ru1; Feng, Wei-Chun2; Wang, Dong1; Liu, Li1
刊名: JOURNAL OF ORGANIC CHEMISTRY
发表日期: 2016-07-01
卷: 81, 期:13, 页:5337-5344
收录类别: SCI
英文摘要: A highly efficient and facile cobalt-catalyzed C-H activation and peroxidation of 2-oxindoles was reported, which provides a new pathway for the synthesis of biologically active 3-peroxy-2-oxindoles from readily available starting materials in excellent chemical yields. The resulting products could be further transformed into various substituted 3-peroxyoxindoles in good to excellent yields. The developed method has been successfully applied to the synthesis of the natural product (+/-)-N-[2(3-hydroxy-2-oxo-2,3-dihydro-1H-indol-3yl)ethyl]acetamide.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35606
Appears in Collections:分子识别与功能实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, BNLMS, Beijing 100190, Peoples R China
2.Chem Technol Acad Shandong Prov, Jinan 250014, Peoples R China
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