中国科学院化学研究所机构知识库
Advanced  
ICCAS OpenIR  > 工程塑料实验室  > 期刊论文
题名: A practical ethylene polymerization for vinyl-polyethylenes: synthesis, characterization and catalytic behavior of alpha,alpha '-bisimino-2,3:5,6-bis(pentamethylene)pyridyliron chlorides
作者: Du, Shizhen1, 2; Wang, Xinxin1, 2; Zhang, Wenjuan1, 2, 3; Flisak, Zygmunt1, 2; Sun, Yang1, 2; Sun, Wen-Hua1, 2, 4
刊名: POLYMER CHEMISTRY
发表日期: 2016
卷: 7, 期:25, 页:4188-4197
收录类别: SCI
英文摘要: A series of alpha,alpha'-bis(arylimino)-2,3:5,6-bis(pentamethylene) pyridyliron chlorides was synthesized in a onepot reaction and characterized by FT-IR and elemental analysis as well as X-ray crystallography for one representative iron complex, where the Fe center adopts a distorted square pyramidal geometry with three coordinating nitrogen and two chlorine atoms. The iron precatalysts, upon treatment with either methylaluminoxane (MAO) or modified methylaluminoxane (MMAO), exhibit high activities in the range of 10(7) g of PE per mol of Fe per h toward ethylene polymerization, yielding highly linear and, more importantly, vinyl-polyethylenes. The correlation between the structural features of iron complexes and their catalytic activities was also investigated.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35536
Appears in Collections:工程塑料实验室_期刊论文

Files in This Item:

There are no files associated with this item.


作者单位: 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
3.Beijing Inst Fash Technol, Sch Mat Sci & Engn, Beijing 100029, Peoples R China
4.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[Du, Shizhen]'s Articles
[Wang, Xinxin]'s Articles
[Zhang, Wenjuan]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[Du, Shizhen]‘s Articles
[Wang, Xinxin]‘s Articles
[Zhang, Wenjuan]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Copyright © 2007-2017  中国科学院化学研究所 - Feedback
Powered by CSpace