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题名: Accessing highly linear polyethylenes by 2-(1-aryliminoethyl)-7-arylimino-6,6-dimethylcyclopenta[b]pyridylchromium(III) chlorides
作者: Zhang, Youfu1, 2; Huang, Chuanbing2, 3; Hao, Xiang2; Hu, Xinquan1; Sun, Wen-Hua2, 3, 4
刊名: RSC ADVANCES
发表日期: 2016
卷: 6, 期:94, 页:91401-91408
收录类别: SCI
英文摘要: A series of 2-(1-aryliminoethyl)-7-arylimino-6,6-dimethylcyclopenta[b] pyridylchromium(III) chlorides (aryl = 2,6-Me2Ph (Cr1), 2,6-Et2Ph (Cr2), 2,6-i-Pr2Ph (Cr3), 2,4,6-Me3Ph (Cr4), 2,6-Et-2-4-MePh (Cr5)) was synthesized and characterized using FT-IR and elemental analysis, and the molecular structure of complex Cr1 was confirmed by using single-crystal X-ray diffraction to present a distorted octahedral geometry around the chromium center. Upon activation with modified methylaluminoxane (MMAO) or ethylaluminium sesquichloride (EASC), all chromium pre-catalysts exhibit good activities towards ethylene polymerization for the highly linear polyethylene.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35475
Appears in Collections:工程塑料实验室_期刊论文

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作者单位: 1.Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Zhejiang, Peoples R China
2.Chinese Acad Sci, Key Lab Engn Plast, Beijing Natl Lab Mol Sci, Inst Chem, Beijing 100190, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
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