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题名: Efficient Catalyst for Both Suzuki and Heck Cross-Coupling Reactions: Synthesis and Catalytic Behaviour of Geometry-Constrained Iminopyridylpalladium Chlorides
作者: Tang, Yujie1; Zeng, Yanning2, 3; Hu, Qingxia1; Huang, Fang1, 2, 3; Jin, Liqun1; Mo, Weimin1; Sun, Nan1; Hu, Baoxiang1; Shen, Zhenlu1; Hu, Xinquan1, 4; Sun, Wen-Hua2, 3, 4
关键词: Iminopyridyl complexes ; Palladium ; Heck reaction ; Suzuki reaction
刊名: ADVANCED SYNTHESIS & CATALYSIS
发表日期: 2016-08-18
卷: 358, 期:16, 页:2642-2651
收录类别: SCI
英文摘要: A series of geometry-constrained iminopyridyl-palladium chlorides were synthesized and characterized. These phosphine-free palladium complexes were explored for their catalytic activities in both Suzuki and Heck cross-coupling reactions, achieving turnover numbers as high as 106 towards various aryl bromides, even those containing various functionalities. In addition, the influence of substituents with steric and electronic factors was reflected by the differences observed in their activities.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35382
Appears in Collections:工程塑料实验室_期刊论文

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作者单位: 1.Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310032, Zhejiang, Peoples R China
2.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100190, Peoples R China
3.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
4.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
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