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题名: Reversible CO Dissociation of Tricarbonyl Iodide [Fe]-Hydrogenase Models Ligating Acylmethylpyridyl Ligands
作者: Hu, Bowen1; Chen, Xiangyang2, 3; Gong, Dawei1; Cui, Wen1; Yang, Xinzheng2; Chen, Dafa1
刊名: ORGANOMETALLICS
发表日期: 2016-09-12
卷: 35, 期:17, 页:2993-2998
收录类别: SCI
英文摘要: A combined experimental;and computational investigation of the CO dissociation properties of three [Fe]-hydrogenase models, [(2-CH2CO-6-HOC5H3N)Fe(CO)(3)I] (1), [(2-CH2CO-6-MeOC5H3N)Fe(CO)(3)I] (2), and [(2-CH2CO-6-tBuOC(5)H(3)N)Fe(CO)(3)I] (3), shows equilibria of tricarbonyl and dicarbonyl complexes in solution. In CH3CN, 1 transforms to the solvated product [(2;CH2CO-6-HOC5H3N)Fe-(CO)(2)(CH3CN)I] (7). The reactivity of 2 with PPh3 was also explored; giving [(2-CH2CO-6,MeOC5H3N)Fe(CO)(2)(PPh3)I] (8) via, one CO substitution by PPh3.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35256
Appears in Collections:分子动态与稳态结构实验室_期刊论文

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作者单位: 1.Harbin Inst Technol, MIIT Key Lab Crit Mat Technol New Energy Convers, Sch Chem & Chem Engn, Harbin 150001, Heilongjiang, Peoples R China
2.Chinese Acad Sci, Beijing Natl Lab Mol Sci, State Key Lab Struct Chem Unstable & Stable Speci, Inst Chem, Beijing 100190, Peoples R China
3.Univ Chinese Acad Sci, Beijing, Peoples R China
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