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题名: Z-Selective Synthesis of gamma,delta-Unsaturated Ketones via Pd-Catalyzed Ring Opening of 2-Alkylenecyclobutanones with Arylboronic Acids
作者: Zhou, Yao1; Rao, Changqing1; Song, Qinling1, 2
刊名: ORGANIC LETTERS
发表日期: 2016-08-19
卷: 18, 期:16, 页:4000-4003
收录类别: SCI
英文摘要: Pd-catalyzed 1,2-addition (instead of 1,4-addition) of arylboronic acids to 2-alkylenecyclobutanones followed by beta-carbon elimination from the resulting palladium cyclobutanolates to afford gamma,delta-unsaturated ketones was developed. The desired gamma,delta-unsaturated ketones were obtained in good to excellent yields with Z/E selectivities of up to >99:1 and a broad spectrum of functional group tolerability.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35233
Appears in Collections:其它_期刊论文

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作者单位: 1.Huaqiao Univ, Inst Next Generat Matter Transformat, Coll Chem Engn, Coll Mat Sci & Engn, 668 Jimei Blvd, Xiamen 361021, Fujian, Peoples R China
2.Inst Chem, Natl Lab Mol Sci, Beijing 100190, Peoples R China
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