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题名: Surface Host-Guest Supramolecular Assemblies on Porphyrin-Based Covalent Organic Grids
作者: Liu, Xuan-He1, 2, 3; Yue JieYu(岳婕妤)1, 2, 4; Mo, Yi-Ping1, 2, 4; Yao, Yi4, 6; Zeng, Cheng4, 5; Chen, Ting1, 2; Yang, Hui-Juan1, 2; Wang, Zhao-Hui5; Wang, Dong1, 2; Wan, Li-Jun1, 2
刊名: JOURNAL OF PHYSICAL CHEMISTRY C
发表日期: 2016-07-28
卷: 120, 期:29, 页:15753-15757
收录类别: SCI
英文摘要: The design and construction of stable porous networks featuring tunable cavities for selective guest inclusion remains a great challenge in construction of functional miniature devices. Herein we report on construction and guest inclusion of stable 2D porphyrin-based molecular square grids connected by imine bonds showing crystalline pattern with periodic square cavities. Diperylene diimides molecules can be decorated into the square pores of the porphyrin-based molecular template on HOPG surfaces. The periodicity control over the covalent molecular grid and thus that of guest molecules is demonstrated by changing the building block. The preparation of robust host-guest systems may facilitate the fabrication of molecular miniature devices with designable properties.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35230
Appears in Collections:分子纳米结构与纳米技术实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China
2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
3.China Univ Geosci Beijing, Sch Sci, Beijing 100083, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
5.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Organ Solids, Beijing 100190, Peoples R China
6.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China
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