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题名: Transition from a Metal-Localized Mixed-Valence Compound to a Fully Delocalized and Bridge-Biased Electrophore in a Ruthenium-Amine-Ruthenium Tricenter System
作者: Tang, Jian-Hong1, 2; Shao, Jiang-Yang1; He, Yan-Qin1; Wu, Si-Hai1; Yao, Jiannian1, 2; Zhong, Yu-Wu1, 2
关键词: density functional calculations ; electrochemistry ; electron transfer ; mixed-valence compounds ; ruthenium
刊名: CHEMISTRY-A EUROPEAN JOURNAL
发表日期: 2016-07-18
卷: 22, 期:30, 页:10341-10345
收录类别: SCI
英文摘要: A series of cyclometalated diruthenium complexes with a redox-active amine bridge were synthesized. Depending on the terminal ligands of the ruthenium components and the substituent on the amine unit, the one-electron-oxidized state can be either in the form of a weakly or strongly coupled mixed-valence diruthenium complex, a fully charge-delocalized three-center system, or a bridge-biased electrophore. This transition among different electronic forms was supported by electrochemistry, near-infrared absorption, electron paramagnetic resonance, and density functional theory analysis.
语种: 英语
内容类型: 期刊论文
URI标识: http://ir.iccas.ac.cn/handle/121111/35208
Appears in Collections:光化学实验室_期刊论文

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作者单位: 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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